Vice President Kamala Harris and second gentleman Douglas Emhoff will host the WNBA champion Aces next week, the White House announced.
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Her arrest came at a time of heightened tensions between Moscow and Washington, just days before Russia sent troops into Ukraine.
Secretary of State Antony Blinken also said he expects to speak with his Kremlin counterpart for the first time since before Russia invaded Ukraine.
She has been detained in Russia since February, and the U.S. government is under pressure at home to do more to secure her freedom.